Yes you can. You'll need a printer that supports this, though.
Here is a list of printers that you can use to print directly onto CDs or DVDs with Acoustica CD/DVD Label Maker.
You'll also need special printable discs. They're usually labeled as printable and have white surfaces. They generally come in either inkjet or thermal varieties; be sure to get the right kind for your printer (the vast majority of CD label printers are inkjet; that"s probably what you've got).
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